首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2300篇
  免费   778篇
  国内免费   116篇
化学   482篇
晶体学   50篇
力学   168篇
综合类   37篇
数学   280篇
物理学   2177篇
  2024年   2篇
  2023年   34篇
  2022年   62篇
  2021年   71篇
  2020年   88篇
  2019年   69篇
  2018年   74篇
  2017年   106篇
  2016年   119篇
  2015年   131篇
  2014年   185篇
  2013年   268篇
  2012年   159篇
  2011年   195篇
  2010年   155篇
  2009年   148篇
  2008年   153篇
  2007年   165篇
  2006年   128篇
  2005年   129篇
  2004年   93篇
  2003年   90篇
  2002年   89篇
  2001年   60篇
  2000年   72篇
  1999年   52篇
  1998年   63篇
  1997年   44篇
  1996年   41篇
  1995年   35篇
  1994年   23篇
  1993年   14篇
  1992年   17篇
  1991年   13篇
  1990年   7篇
  1989年   7篇
  1988年   4篇
  1987年   4篇
  1986年   4篇
  1985年   6篇
  1984年   7篇
  1982年   1篇
  1981年   2篇
  1980年   1篇
  1978年   1篇
  1976年   1篇
  1971年   2篇
排序方式: 共有3194条查询结果,搜索用时 15 毫秒
11.
Distance between two vertices is the number of edges in a shortest path connecting them in a connected graph G. The transmission of a vertex v is the sum of distances from v to all the other vertices of G. If transmissions of all vertices are mutually distinct, then G is a transmission irregular graph. It is known that almost no graphs are transmission irregular. Infinite families of transmission irregular trees of odd order were presented in Alizadeh and Klav?ar (2018). The following problem was posed in Alizadeh and Klav?ar (2018): do there exist infinite families of transmission irregular trees of even order? In this article, such a family is constructed.  相似文献   
12.
The effect of Re addition on the microstructure and hardening behaviour of the dual two-phase Ni3Al (L12) and Ni3V (D022) intermetallic alloy was investigated by scanning electron microscopy, transmission electron microscopy and Vickers hardness test. The two-phase eutectoid microstructure accompanying the Re-rich precipitates were observed in the channel region of the alloys in which Re substituted for Ni but not in those in which Re substituted for Al and V. The concomitant addition of Nb (or Ta) with Re more stabilized the two-phase eutectoid microstructure and consequently more induced the fine precipitates in the channel region. The annealing at temperatures below the eutectoid temperature was necessary to induce the fine precipitates in the channel region and thereby result in the precipitation hardening. The fine precipitation in the channel region and related hardening was attributed to the alloying feature so that Re is soluble in the A1 (fcc) phase at high temperatures and becomes less soluble in the two intermetallic phases decomposed from the A1 phase at low temperatures.  相似文献   
13.
The LiRh-type crystal structure of the equiatomic intermetallic compound IrZn turns out to be a competitor to the otherwise energetically favored CsCl-type structures of congeneric transition metal zinc phases, thus enlightening the structural impact of element-specific factors beyond the Hume-Rothery concept.  相似文献   
14.
ABSTRACT

Optical diffusers are promising diffusing materials in the optical devices such as monitors, projectors, fibre optics, light-emitting diode (LED) systems and liquid crystal displays (LCDs). We report optical diffusers comprising uniformly distributed nano-sized polymer balls/nematic liquid crystals (LCs) by ultraviolet (UV) click reaction of ene monomer and thiol monomer. By optimising the mass ratio 1:1 of ene and thiol, of which the average diameter of the corresponding nano-sized polymer balls is about 900 nm, relatively high optical transmission and haze with 88.99% and 94.49% are yielded, respectively. Furthermore, by controlling the curing time, the average diameter of nano-sized polymer balls can be reduced to 810 nm, and the developed film exhibits high transmission (98.49%) without sacrificing the high haze (91.77%). This paper demonstrates that UV click reaction is an economical approach to fabricate optical diffusers in a controllable manner.  相似文献   
15.
In this work, we designed and studied a feasible dual-layer binary metagrating, which can realize controllable asymmetric transmission and beam splitting with nearly perfect performance. Owing to ingenious geometry configuration, only one meta-atom is required to design for the metagrating system. By simply controlling air gap between dual-layer metagratings, high-efficiency beam splitting can be well switched from asymmetric transmission to symmetric transmission. The working principle lies on gap-induced diffraction channel transition for incident waves from opposite directions. The asymmetric/symmetric transmission can work in a certain frequency band and a wide incident range. Compared with previous methods using acoustic metasurfaces, our approach has the advantages of simple design and tunable property and shows promise for applications in wavefront manipulation, noise control and one-way propagation.  相似文献   
16.
The aim of this paper is to establish a well‐posedness result for a boundary value problem of transmission‐type for the standard and generalized Brinkman systems in two Lipschitz domains in , the former being bounded, and the latter, its complement in . As a first step, we establish a well‐posedness result for a transmission problem for the standard Brinkman systems on complementary Lipschitz domains in by making use of the Potential theory developed for such a system. As a second step, we prove our desired result (in L2‐based Sobolev spaces) by using a method based on Fredholm operator theory and the well‐posedness result from the previous step.  相似文献   
17.
Vector‐borne diseases, such as leishmaniasis, dengue, malaria, and yellow fever, transmitted by microparasites show periodic fluctuations in their prevalence. The novelty of this research is to assess the relationship between the vector feeding preference for an infectious host and the annual seasonal transmission through a vector‐host mathematical model. For the first time, numerical simulations illustrate that by increasing the vector feeding preference value in the transmission dynamics, periodic fluctuations accentuate and the endemic equilibrium average increases in vector and host populations. Moreover, increasing the vector feeding preference value, the amplitude strengthens for the infectious host and vector populations. This periodic behavior shows a similar pattern with the Peruvian incidence data from 2000 to 2016 for Andean cutaneous leishmaniasis provided by the Ministry of Health of Peru (MINSA). In addition, using the Floquet theory, the time average method and the linear operator method provides for the first time that the basic reproduction number for a nonautonomous system depends explicitly on the vector feeding preference for the infectious host. The nonautonomous model system shows that is a threshold parameter for the local stability of the disease‐free periodic solution. Therefore, the vector feeding preference is an important factor that should be considered and attended to for future research. Public and veterinary health in Peru and other countries should consider the vector feeding preference for specific host to vector control.  相似文献   
18.
A new preparation route is developed for the synthesis of needle-like crystals of [Au(S2CNH2)2]SCN, which avoids disproportionation of the AuI salt used as a starting material. In the crystal structure, the two crystallographically independent AuIII centers are in a square-planar environment of two S2CNH2 ligands. The Hirshfeld surface analysis reveals the presence of noncovalent intermolecular S⋅⋅⋅S interactions, which are essential for the spatial arrangement of the molecules. Density functional theory (DFT) calculations including dispersion and damping corrections result in a unit cell volume very close to the value determined experimentally. Thermal decomposition in an inert atmosphere generates black needles with lengths of up to 500 μm. X-ray powder diffraction and pair distribution function analyses demonstrate that the needles are composed of nanosized crystals with a volume-weighted average domain size of 20(1) nm. According to results of X-ray photoemission experiments, the black needles are covered by a nitrogen-rich carbon nitride with composition near (CN)2N. 13C solid-state NMR investigations indicate that two different carbon species are present, with signals corresponding well to heptazine units as in melon and triazine units as in poly(triazin imide) type compounds. Scanning transmission electron microscopy tomography evidences that the needles are composed of slightly elongated nanoparticles.  相似文献   
19.
Nanoparticles have an immense importance in various fields, such as medicine, catalysis, and various technological applications. Nanoparticles exhibit a significant depression in melting point as their size goes below ≈10 nm. However, nanoparticles are frequently used in high temperature applications such as catalysis where temperatures often exceed several 100 degrees which makes it interesting to study not only the melting temperature depression, but also how the melting progresses through the particle. Using high‐resolution transmission electron microscopy, the melting process of gold nanoparticles in the size range of 2–20 nm Au nanoparticles combined with molecular dynamics studies is investigated. A linear dependence of the melting temperature on the inverse particle size is confirmed; electron microscopy imaging reveals that the particles start melting at the surface and the liquid shell formed then rapidly expands to the particle core.  相似文献   
20.
王淦平  李春霞  金晓  黄华  刘振帮 《强激光与粒子束》2020,32(5):053003-1-053003-4
分析了采用单一同轴磁场时强流相对论多注阴极的侧端发射问题,研究了在不同磁场内半径和多注漂移管长度情况下多注电子束的传输效率。研究发现:由于引导磁场尺寸有限,高压下多注阴极杆及多注阴极柱的电子束发射是影响多注电子束传输效率的主要因素,且该部分电子束对多注漂移管入口管壁的轰击直接影响了多注速调管的重频能力。设计了采用永磁铁和同轴磁场组合工作的强流相对论多注二极管,理论分析和模拟计算证明:基于组合磁场的多注二极管可明显减弱甚至抑制多注阴极发射球头以外的电子束发射,并且组合磁场的磁场位形和强度可满足强流相对论多注电子束的高效、稳定传输。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号